Research
Fabrication and Functionalization of Nanomaterials
One-Dimensional (1D) Nanomaterials: Carbon nanotubes (CNTs), CNTs/B4C, CNTs/SiC core/shell nanostructures, NiCo2S4, copper nanowires, ZnO nanobelts, etc. have been fabricated using hydrothermal/solvothermal reactions, electrochemical deposition, chemical vapor deposition (CVD) approaches towards various applications. Current research interest on 1D nanomaterials lies in bimetallic, trimetallic, and high-entropy alloying nanowires for catalysis.
CNT Arrays
CNT/B4C Core/Shell
NiCo2S4 Nanowires
Two-Dimensional (2D) Nanomaterials: MoS2, MoSe2, h-BN, Graphene, SnSe2, TiS2, TaS2, MoS2/WSe2 and h-BN/graphene heterostructures, MoαTaβTiγVδWεTe2 (α, β, γ, δ, ε<0,2 and α+β+γ+δ+ε=1), etc. have been synthesized via CVD and solid-state reaction (SSR) reactions. Current interest on 2D nanomaterials is limited to fabrication of heterostructures and high-entropy materials for mechanical investigation, hydrogen evolution reactions (HER), and electronic devices.
MoSe2
h-BN
MoS2/WSe2 on Graphene/h-BN
Three-Dimensional (3D) Nanomaterials: CNTs/graphene, MOFs, and metallic nanowire arrays have been fabricated with CVD, hydrothermal/solvothermal reactions, and electrochemical deposition, respectively, for either mechanical strengthening, CO2 adsorption, or water treatment. Current interest in 3D nanomaterials is to scale up nanomaterials to bulk porous structure for practical applications.
MOFs
Cu Nanowire Arrays
3D CNTs/Graphene
Mechanics of Advanced Nanomaterials and Nanocomposites
Mechanics of Nanomaterials: 1D, 2D, and 3D nanomaterials and their hybrids have been intensively investigated as emerging materials for future devices. Mechanical stability of each nanocomponent is critical to the reliability of the fabricated devices. To date, theoretical and experimental mechanics of CNTs, CNT/SiC, CNT/B4C, MoSe2, h-BN, graphene/CNTs have been investigated through in situ and ex situ mechanical testing enabled by atomic force microscope, nanoindention, scanning and transmission electron microscopes.
ZnO Nanobelt Indented by AFM
Fracture in CNT/SiC
In situ Fracture of h-BN
Interface Mechanics of Nanocomposites: Sustainable effort has been devoted to improving fracture toughness and fracture strength of composites and hybrid materials intrinsically and extrinsically. For example, the interface shear strength was investigated on polymer derived ceramic reinforced by either CNT or CNT deposited with noncontinuous Al2O3 and HfO2 nanoislands. The interfaced bonding strength between CNTs and graphene was also measured on CNTs/graphene.
Debond CNT/Al2O3 out of PDC
Debond of CNT out graphene
Hydrogen bonding measurement
Nanomaterials and Nanocomposites for Advanced Applications
1D, 2D, and 3D nanomaterials have been scaled up, doped, and functionalized towards energy storage, carbon dioxide capture and reduction, hydrogen generation, water desalination and air filtration. Specifically, to largely utilize abundant renewable biomass and reduce biowaste, selected biomass has been converted into porous carbon skeleton to support nanomaterials growth to build up 3D hybrid materials for practical applications.